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High-Resolution Fourier Transform Spectra of HDS in the Regions of the Bands ν1and 2ν1/ν2+ ν3

✍ Scribed by O.N. Ulenikov; G.A. Onopenko; I.M. Olekhnovitch; S. Alanko; V.-M. Horneman; M. Koivusaari; R. Anttila

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 404 KB
Volume: 189
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7518

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✦ Synopsis

High-resolution spectrum of the HDS molecule was recorded with the Bruker Fourier spectrometer in Oulu in the regions of the n 1 and 2n 1 /n 2 / n 3 absorption bands. Fine rotational structure of the n 1 band was analyzed with the model of an isolated vibrational state, while in the analysis of the 2n 1 and n 2 / n 3 bands it was necessary to take into account the resonance interactions between these two bands. Comparison of the experimentally determined parameters is made with the deductions of the expanded local mode approach.

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