High-resolution 1H and 11B NMR studies of 1,2- and 1,7-B10C2H12
โ Scribed by A.R Garber; G.M Bodner; L.J Todd; A.R Siedle
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 447 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-2364
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๐ SIMILAR VOLUMES
## Abstract 10,12โDihydroisoindolo[1,2โb]quinazolineโ12โone (1) was prepared and fully examined by ^1^H and ^13^C NMR spectroscopy in CDCl~3~ and DMSOโd~6~ solution.
The cluster "B chemical shifts in members of the important class of closo-3,1,2-metalladicarbaboranes were previously unassigned, and their cluster 'H chemical shifts previously unmeasured. The use of 1' 'B-' 'BJ-COSY and 'H-{"B} NMR spectroscopy to measure and assign the cluster "B and 'H chemical
Regioselective deuteration of 1-X-C 2 B 10 H 12 (X โซืกโฌ 2, 7) cage systems with C 6 D 6 /AlCl 3 is correlated to ab initio calculational results on a [C 2 B 10 H 13 ] โซืโฌ intermediate. Full geometry optimizations of pertinent [C 2 B 10 H 13 ] โซืโฌ isomers, derived from each of the two 1-X-C 2 B 10 H 1