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High-pressure variable temperature Raman studies on hexamethyl benzene crystals

✍ Scribed by J. S. Bodenheimer; W. F. Sherman; G. R. Wilkinson

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
343 KB
Volume
7
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

The Raman spectra of hexamethyl benzene and HMB‐d~18~ have been recorded as a function of temperature between 4 K and 400 K and as a function of pressure up to 8kbar. In the low‐frequency region, librational and torsional modes have been distinguished. The spectra indicate a phase transition to a high‐pressure phase IV. The polarized infrared spectra of single crystals have also been observed at different temperatures.

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