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High-Pressure Synthesis of a Gallium Oxonitride with a Spinel-Type Structure.

✍ Scribed by Isabel Kinski; Gerhard Miehe; Gunter Heymann; Ralf Theissmann; Ralf Riedel; Hubert Huppertz


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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new title compound are obtained from a mixture of La2O3, B2O3, and LaF3 in the molar ratio 5:6:2 (Walker-type multianvil apparatus, 6 GPa, 1300 Β°C, 10 min). La4B4O11F2 crystallizes in the monoclinic space group P21/c with Z = 8. The crystal structure contains BO3 groups connected by BO4 tetrahedra v