High-pressure synthesis and crystal structure of γ-Mo2N
✍ Scribed by Tetsuya Kawashima; Eiji Takayama-Muromachi; Paul F. McMillan
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 172 KB
- Volume
- 460-462
- Category
- Article
- ISSN
- 0921-4534
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Two new high-pressure phases of binary boron+sulfur compounds, B 2 S 3 -II and B 2 S 3 -III, were synthesized at 3+6.2 GPa. A single crystal of B 2 S 3 -III was grown and the structure was determined (tetragonal, space group I4 1 /a, a ؍ 16.086(2) A s , c ؍ 30.488(4) A s ; V ؍ 7888(1) A s 3 ,
Crystalline, poorly crystalline, and single-layer MoS 2 were synthesized using a hydrothermal method at low temperature (170+2003C) through changing pressure and time. XPS, XRD, and TEM were used to study the products. It was found that the stacking of the single layers was closely related to the pr