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High Pressure Promoted Cycloadditions of Enol Ethers and 3-Aryl-2-cyano-2-propenoates.

✍ Scribed by Rene W. M. Aben; Rene de Gelder; Hans W. Scheeren


Publisher
John Wiley and Sons
Year
2003
Weight
246 KB
Volume
34
Category
Article
ISSN
0931-7597

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High-Pressure Promoted Cycloadditions of
✍ René W. M. Aben; René  de Gelder; HansΒ W. Scheeren πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 147 KB

The high-pressure promoted cycloadditions of enol ethers (1) and alkyl 3-aryl-2-cyano-2-propenoates (2) lead stereoselectively in high yields to 2,6-dialkoxy-4-aryl-3,4-dihydro-2Hpyran-5-carbonitriles (3). These cycloadducts have a high potential for further synthesis due to the presence of various

ChemInform Abstract: High-Pressure Promo
✍ R. M. UITTENBOGAARD; J.-P. G. SEERDEN; H. W. SCHEEREN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 1 views

High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers. -The tandem cycloadditions of the nitroalkenes (I) and (V) with ethyl vinyl ether are found to be strongly accelerated under high pressure. The reactions proceed regioand stereoselectively.