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ChemInform Abstract: Synthesis of Novel Bi- and Tricyclic Heteroactivated β-Lactams by Pressure- Promoted [4 + 2]/[3 + 2] Tandem Cycloadditions of Enol Ethers and Nitrostyrene

✍ Scribed by G. J. T. Kuster; F. Kalmoua; J. W. Scheeren

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200014247

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✍ George J. Kuster; Faysal Kalmoua; Rene de Gelder; Hans W. Scheeren 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

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ChemInform Abstract: High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers.

✍ R. M. UITTENBOGAARD; J.-P. G. SEERDEN; H. W. SCHEEREN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers. -The tandem cycloadditions of the nitroalkenes (I) and (V) with ethyl vinyl ether are found to be strongly accelerated under high pressure. The reactions proceed regioand stereoselectively.