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High-pressure NMR study of dynamical solvent effects on the conformational isomerization of 1,1-difluorocyclohexane

✍ Scribed by J. Ashcroft; M. Besnard; V. Aquada; J. Jonas

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 394 KB
Volume: 110
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85456-1

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✦ Synopsis

The trims oi tcmpcrn~ure md prcssurc on rile coniurnmionlri isomerizahn of l.l~i!luoroc~clohcsanc in soluCon IKIW bccu studied using 191: FT NMl< spsctroscopy.

The prcssurc dcpcndcncc of the isomerizaIion of l,l-difluorocyclo-I~exmc in xctoncdb and mcIi~ylc~clohcsanc compared ICI rhe pressure depcndcncc of 111e isomerizarion of cyclohesanc in the sdmc soivcnrs indicates the prcscnce of diclccuic friction cffecrs for l.liiifluoroc~cio!lcsa~~c in a polar solvcnr.

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