An autoclave-type 'H NMR probe has been developed to monitor the carbonization process of such carbonaceous materials as coal and pitch under high pressures up to 10 MPa. In the early stages of the carbonization of pitch, the change in hydrogen aromaticity, fHe, was found to be dependent on the appl
High-temperature high-pressure 1H-NMR study on formation of carbon spherules
โ Scribed by S. Shimokawa; E. Yamada; T. Yokono; J. Yamada; Y. Sanada; M. Inagaki
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 182 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0008-6223
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โฆ Synopsis
Carbon spherules, nuclear magnetic resonance (NMR), coal tar pitch, PVC pitch.
Carbonization under pressure modifies the reaction process so as to give a high carbon yield and also to form a structure in the resultant solid carbon which is different from that formed under normal pressures. Marsh er a/. [ 1,2] reported
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