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High-pressure induced 1,3-dipolar cycloadditions of azides with electron-deficient olefins

โœ Scribed by Anderson, Glen T.; Henry, James R.; Weinreb, Steven M.


Book ID
119998688
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
360 KB
Volume
56
Category
Article
ISSN
0022-3263

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Mechanisms of 1.3-dipolar cycloadditions
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Cycloaddition mechanisms can be separated phenomenologically into three classes. (1) concerted, (2) stepwise--diradical intermediate, and (3) stepwise--zwitterionic intermediate.