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High oxlnation state transition metal carboxylates as acylating agents

โœ Scribed by Joel Recht; Brett I. Cohen; Alan S. Goldman; Joachim Kolm


Book ID
104221862
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
292 KB
Volume
31
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The formation of amide bonds from the reaction of metal carboxylates with amines was observed for the first time; complexes of titanium(IV), zirconium(IVl and tantalum(\r) were investigated.


๐Ÿ“œ SIMILAR VOLUMES


Metal ion catalysis in acyl and phosphor
โœ Anatoly K. Yatsimirsky ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 438 KB

Interpretation of the role of metal ions in catalysis in terms of direct binding of the catalyst to the transition state of the uncatalyzed reaction allows one to view transition states as ligands and to apply the concepts elaborated for analysis of stability of coordination compounds to reactivity.