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High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] · Me2CO

✍ Scribed by Gianfranco Ciani; Massimo Moret; Angelo Sironi; Secondo Martinengo

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
632 KB
Volume
363
Category
Article
ISSN
0022-328X

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✍ Jasmine Po-Kwan Lau; Yan-Juan Gu; Wing-Tak Wong 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB 👁 1 views

## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,