A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3−
✍ Scribed by Secondo Martinengo; Gianfranco Ciani; Angelo Sironi
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 226 KB
- Volume
- 358
- Category
- Article
- ISSN
- 0022-328X
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## Abstract A direct and high‐yield synthetic route for a novel dodecanuclear osmium‐rhodium mixed‐metal cluster is presented. The redox properties of the cluster were examined, and it was found that the anion behaves as an “electron reservoir”. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,
The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit