Nitrogen ion implantation in titanium using plasma immersion ion implantation (PIII) is investigated at a pulse voltage of 15 keV and elevated temperatures between 300 and 750 °C. Starting the implantation at room temperature leads to the parallel formation of TiN and Ti 2 N, as observed by X-ray di
High fluence nitrogen implantation in Al/Ti multilayers
✍ Scribed by D. Peruško; M. Milosavljević; V. Milinović; B. Timotijević; A. Zalar; J. Kovač; B. Praček; C. Jeynes
- Book ID
- 103862831
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 221 KB
- Volume
- 266
- Category
- Article
- ISSN
- 0168-583X
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✦ Synopsis
We have studied the effects of high fluence nitrogen ion implantation on the structural changes in Al/Ti multilayers, with the aim of achieving multilayered metal-nitrides. The starting structures consisted of 10 alternate sputter-deposited Al and Ti films, with a total thickness of 270 nm, on (1 0 0) Si substrates. They were implanted with 200 keV N þ 2 , to 1 Â 10 17 and 2 Â 10 17 at/cm 2 , the projected range being around half-depth of the multilayers. Structural characterization was performed by Rutherford backscattering, Auger electron spectroscopy and transmission electron microscopy. It was found that ion implantation to the higher fluence induces a full intermixing of Al/Ti layers, resulting in a multilayered structure with different content of Al, Ti and N. The applied method can be interesting for preparation of graded (Al,Ti)N multilayers, with a controlled content of nitrogen and a controlled level of Al-Ti intermixing within the structures.
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