High-field X-ray diffraction and high-pressure magnetization measurements of the pseudobinary compound Ce(Fe0.9Co0.1)2
โ Scribed by Keiichi Koyama; Kouichi Fukushima; Masaki Yamada; Tsuneaki Goto; Yoshikazu Makihara; Hironobu Fujii; Kazuo Watanabe
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 292 KB
- Volume
- 346-347
- Category
- Article
- ISSN
- 0921-4526
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โฆ Synopsis
The magnetic and structural properties of Ce(Fe 0.9 Co 0.1 ) 2 with the C15 cubic Laves-phase structure have been studied by magnetization measurement in high magnetic fields under high pressures, and powder X-ray diffraction measurement in fields up to 5 T. The C15 cubic structure is distorted to rhombohedral symmetry accompanied with the magnetic phase transition from the ferromagnetic to the antiferromagnetic state, which recovered the C15 structure by applying the magnetic field. The antiferromagnetic phase is induced by the lattice contraction due to hydrostatic pressure. Obtained results suggest that the AFM correlation due to the Ce 4f-Fe 3d hybridization plays an important role on the structural and magnetic properties.
๐ SIMILAR VOLUMES
Single-crystal high-pressure (HP) crystallography is a growing field, but studies on organometallics are relatively rare despite the many interesting behaviors inferred from HP spectroscopy. [1] Molecular solids, being held together by [