Staggered to Eclipsed Conformational Rearrangement of [Co2(CO)6(PPh3)2] in the Solid State: An X-ray Diffraction Study at High Pressure and Low Temperature

✍ Scribed by Nicola Casati; Piero Macchi; Angelo Sironi

• Publisher: John Wiley and Sons
• Year: 2005
• Tongue: English
• Weight: 117 KB
• Volume: 117
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/ange.200502241

✦ Synopsis

Single-crystal high-pressure (HP) crystallography is a growing field, but studies on organometallics are relatively rare despite the many interesting behaviors inferred from HP spectroscopy. [1] Molecular solids, being held together by [