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High Efficiency and Enantioselectivity in the Rh-Catalyzed Conjugate Addition of Arylboronic Acids Using Monodentate Phosphoramidites.

✍ Scribed by Jean-Guy Boiteau; Adriaan J. Minnaard; Ben L. Feringa

Publisher: John Wiley and Sons
Year: 2004
Weight: 152 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200415054

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In 2000, three research groups demonstrated that the widely held view that chiral bidentate ligands are necessary to achieve high enantioselectivity in rhodium-catalyzed hydrogenations needs revision. Monodentate phosphonites, [1a] phosphites [1b] and phosphoramidites [1c] proved to be highly versat