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High diastereoselectivity in lewis acid mediated aldol condensations using thioester silyl ketene acetals.

✍ Scribed by Cesare Gennari; Anna Bernardi; Silvia Cardani; Carlo Scolastico

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 248 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89140-6

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✦ Synopsis

BF30Et2 mediated aldol condensations of thioester silyl ketene acetals are stereoconvergent, and exhibit high internal (anti) and relative (Cram) diastereoselectivity.

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