Butadiene is polymerized by the catalyst system nickel diisopropylsalicytatei~ooron trifluoride etherate/butyl lithium to high cis-l,4-configuration. A description is given of the effects of (a) changing catalyst component ratios; (b) order of catalyst addition; and (c) change of solvent, on microst
✦ LIBER ✦
High cis-1,4 polybutadiene—III. The catalyst system nickel dusopropylsalicylate, boron trifluoride etherate, lithium tetrabutyl boron
✍ Scribed by C. Dixon; E.W. Duck; D.K. Jenkins
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 272 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0014-3057
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A description is given of the behaviour of the catalyst for high cis-l,4-polybutadiene (nickel di/sopropylsalicylate-boron trifiuoride etherate--lithium butyl) in the presence of 1,2-butadiene, methyl acetylene, 1-butene and various organic nitro compounds.