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High activity Ziegler–Natta catalysts for the preparation of ethylene copolymers

✍ Scribed by T. E. Nowlin; Y. V. Kissin; K. P. Wagner

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
591 KB
Volume
26
Category
Article
ISSN
0887-624X

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A soluble ethylene catalyst were obtained by mixing a methylene dichloride solution of dichlorobislT-cyclopentadienyl) titanium (Cp2TiCI2) with a heptane solution of ethylaluminium sesquichloride (AlzEt3C13) or of diethylaluminium chloride {AIEt2CI). Ethylene was polymerized using these catalysts; t

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With different structure ligands heterogeneous Ziegler–Natta catalysts for the preparation of copolymer of ethylene and 1-octene with high comonomer incorporation
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Comparison with the conventional ZieglereNatta catalyst TiCl 4 /MgCl 2 (I), the modified supported Zie-glereNatta catalysts (iso-PentylO)TiCl 3 /MgCl 2 (II) and (BzO)TiCl 3 /MgCl 2 (III) were prepared as efficient catalysts for copolymerization of ethylene with 1-octene. The complexes (II) and (III)