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High 1,5-Anti Stereoinduction in Boron-Mediated Aldol Reactions of Methyl Ketones †

✍ Scribed by Dias, Luiz C.; Baú, Rosana Z.; de Sousa, Márcio A.; Zukerman-Schpector, J.


Book ID
126884157
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
83 KB
Volume
4
Category
Article
ISSN
1523-7060

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Remote, 1,5-anti Stereoinduction in the Boron-Mediated Aldol Reactions of β-Oxygenated Methyl Ketones. -The title reaction is investigated with different kinds of aldehydes leading to the desired aldol products with a high level of substrate-based 1,5-stereocontrol. The products are suitable syntho