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HF(B1Σ→X1Σ) UV chemiluminescence from the H+/H+2+F− ion-ion reactions

✍ Scribed by Hung-tai Wang

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
577 KB
Volume
136
Category
Article
ISSN
0009-2614

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✦ Synopsis

Chemiluminescence spectra attributable to the H+/H$ + F-+HF B 'Z ion-ion reactions were obtained in the wavelength region 185-270 nm. The rovibrationally resolved bands were assigned as HF B 'Z (u' , J') to HF X 'X (u", J") transitions with 0 < v' < 4 and 12 d u" Q 16. The corresponding rotational branches all have peaks at high J values. These non-thermal distributions suggest that the corresponding product state v', J' populations reflect the nascent distribution from the ion-ion reactions.

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