The fragmentation of formaldehyde molecular cations: energetics of the dissociation X2CO+(Ã2B1)→CO+(2Σ+)+X2(1Σg+) (X = H,D)

✍ Scribed by Rolf Bombach; Josef Dannacher; Jean-Pierre Stadelmann; Jürgen Vogt

• Publisher: Elsevier Science
• Year: 1980
• Tongue: English
• Weight: 319 KB
• Volume: 76
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(80)80641-5

✦ Synopsis

HeIcr photoelectron-photolon comadence spectroscopy has been apphed to study the dlssoclatton CX20-(A 'B,)-D CO-('T')+Xz('T,) (X = H. D) The measured branchmg ratios and kmenc energy releases reveal that an acnvatloa energy Free pathway IS practically maccessnble I" the absence of auto,on,zat,on