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Hexameric KN2Co [P(CH3)3]3—A Novel Potassium-Dinitrogen Cluster

✍ Scribed by Dr. Reinhard Hammer; Doz. Dr. Hans-Friedrich Klein; Dipl.-Chem. Peter Friedrich; Prof. Dr. Gottfried Huttner


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
230 KB
Volume
16
Category
Article
ISSN
0044-8249

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Co5(CO)11(PR2)3, A Novel Type of Pentanu
✍ Dipl.-Chem. Egbert Keller; Prof. Dr. Heinrich Vahrenkamp 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 241 KB

## Experimmtul (+)-Cataline,( +)-( ):Asolutionof( + ) -( ) ( 1 g)in trifluoroacetic acid (TFA) is treated dropwise with stirring at -15 "C with a solution of VOF3 (0.7g) in TFA (25ml) (deep blue to red-violet coloration). The mixture is stirred for 2 h at -15 to -10°C and, after removal of the col