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A Trihydroxy Tin Group That Resists Oligomerization in the Trinuclear Nickel Cluster [Ni3(μ-P,P′-PPh2CH2PPh2)3(μ3-L)- (μ3-Sn(OH)3)]

✍ Scribed by Eugenio Simón-Manso; Clifford P. Kubiak

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 143 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200462129

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A Trihydroxy Tin Group That Resists Olig

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The conversion of tin chloride reagents into the corresponding hydroxides typically results in the formation of oligomeric tin oxides. [1][2][3] We report herein the preparation and reactivity of a trinuclear nickel cluster that is capped by a m 3 -Sn(OH) 3 group. This is a rare example of a complex

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