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Hexacyclo[6.6.1.02,7.03,12.06,11.09,14]pentadecane and pentacyclo[8.4.0.03,8.03,14.07,11]tetradecane systems from decahydro[1,4;5,8]dimethanoanthracene-11,12-dione

✍ Scribed by Srikrishna, A.; Sunderbabu, G.


Book ID
126194025
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
450 KB
Volume
52
Category
Article
ISSN
0022-3263

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Synthesis of hexacyclo[5.4.1.02,6.03,10.
✍ Paquette, Leo A. ;Nakamura, Koichi ;Engel, Peter πŸ“‚ Article πŸ“… 1986 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 966 KB

Sulfenylation of the dianion of dimethyl tetracyclo[7.2.1 .O4~".Ob~'"]dodeca-2,7-diene-5,I2-dicarboxylate (9) with dimethyl disulfide delivered the exo,exo-bis(methylthi0) derivative 10a. Subsequcnt saponification and oxidative decarboxylation resultcd in transformation to tetracyclo[7.2.1 .04.''.06