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Hexaaqua­nickel(II) bis­[2-(4-carboxy­phen­oxy)propionate] trihydrate

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Chen, Peng-Gang


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
217 KB
Volume
63
Category
Article
ISSN
1600-5368

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In the ionic title compound, [Ni(H 2 O) 6 ](C 8 H 6 NO 5 ) 2 Á5H 2 O, the [Co(H 2 O) 6 ] 2+ cation, (4-nitrophenoxy)acetate anions and water molecules engage in O-HÁ Á ÁO hydrogen bonding, generating a three-dimensional hydrogen-bonded network.

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The title complex, [Co(C 10 H 9 O 5 ) 2 (C 10 H 10 O 5 ) 2 (C 5 H 5 N) 2 ], is a neutral mononuclear complex. The Co II atom, which lies on a centre of symmetry, has a distorted octahedral geometry involving two O atoms of the 3-(4-carboxyphenoxy)propionate groups, two O atoms of the 3-(4-carboxyphe