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Hexaaqua­manganese(II) dichloride 4,4′-bipyridine N,N′-dioxide disolvate dihydrate

✍ Scribed by Song, Hui-Hua ;Ma, Bao-Qing

Book ID
104490095
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
369 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Mn(H 2 O) 6 ]Cl 2 Á-2C 10 H 8 N 2 O 2 Á2H 2 O, consists of one half of the [Mn(H 2 O) 6 ] 2+ cation, with the Mn atom on a centre of inversion, a chloride anion, a 4,4 0 -bipyridine N,N 0 -dioxide solvate and a solvent water molecule. 4,4 0 -Bipyridine N,N 0 -dioxide molecules link [Mn(H 2 O) 6 ] 2+ cations through O-HÁ Á ÁO hydrogen bonds into a two-dimensional sheet. These sheets are further connected by solvent water molecules and Cl À anions into a three-dimensional network via O-HÁ Á ÁCl and O-HÁ Á ÁO hydrogen bonds.

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