In the title compound, [Co(H 2 O) 6 ](C 8 H 6 NO 4 S) 2 , the Co II atom lies on a centre of inversion and is six-coordinate in an octahedral environment. Cations and anions are linked by O-HÁ Á ÁO hydrogen bonds into a three-dimensional network.
Hexaaquacobalt(II) bis(4-nitrophenoxyacetate) pentahydrate
✍ Scribed by Gao, Jin-Sheng ;Li, Bai-Yan ;Hou, Guang-Feng ;Zhang, Yi-Ming ;Yan, Peng-Fei
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 242 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The crystal structure of the title complex, [Co(C 9 H 7 O 5 ) 2 -(C 10 H 8 N 2 ) 2 (H 2 O) 2 ]Á4H 2 O or [Co(4-CPOAH) 2 (4,4 0 -bipy) 2 -(H 2 O) 2 ]Á4H 2 O (4,4 0 -bipy is 4,4 0 -bipyridine and4-CPOAH À is the 4-carboxyphenoxyacetate monoanion), consists of two independent mononuclear molecules that
The crystal structure of the title compound, [Co(H 2 O) 6 ]-(C 8 H 5 O 3 ) 2 Á2H 2 O, consists of octahedral Co II complex cations that interact with the anions and uncoordinated water molecules, forming a tightly held, hydrogen-bonded layer. The Co II complex cation lies on a special position of si