In the title compound, C 15 H 13 ClN 2 O 3 ÁH 2 O, the molecule adopts a trans configuration with respect to the C N double bond. The dihedral angle between the two rings is 15.03 (3) . The structure is stabilized by intramolecular O-HÁ Á ÁN and intermolecular N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds,
✦ LIBER ✦
Hexaaqua(4-chloro-3-formylbenzenesulfonato)calcium(II) 4-chloro-3-formylbenzenesulfonate monohydrate
✍ Scribed by Wallace, Dawn ;Reglinski, John ;Taylor, Michelle K. ;Kennedy, Alan R.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 153 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The supramolecular structure of the title molecule, [Ca(C 7 H 4 -ClO 4 S)(H 2 O) 6 ](C 7 H 4 ClO 4 S)ÁH 2 O, contains alternating organic and inorganic layers along the b direction. The sulfonate group on one of the aryl units is coordinated to Ca, while the other does not form any interaction with a Ca atom.
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