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Heterotricyclodecane XXII 2-Aza-7-thia-isotwistane

✍ Scribed by Henry Szczepanski; Camille Ganter

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
616 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis

2‐Aza‐7‐thia‐isotwistanes.

2‐Aza‐7‐thia‐isotwistanes were synthesized either starting from suitable 9‐thiabicyclo[3.3.1]nonenes by olefin‐amination (1 → 4, 2 → 5, 3 → 6, 8 → 10 and 9 → 11) as well as by intramolecular substitution (25 → 26) or by molecular rearrangement starting from twistanes (21 → 19 and 22 → 10). From the isotwistanes thus obtained several other compounds (7, 12–18, 20, 23 and 24) were prepared, too.

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