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Heteronuclear NMR studies of cobalamins. 6. The nucleotide loop of base-off cobalamins and the nature of the base-off species

✍ Scribed by Brown, Kenneth L.


Book ID
127256938
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
1005 KB
Volume
109
Category
Article
ISSN
0002-7863

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The emission Mijssbauer spectra of "base on" and '&base off' forms of the cyanocob(III)aIamin (vitamin B1z) and the cob(II)alamin (B1zr) and the cob(I)alamin (B1& are studied. The s-electron density on the daughter iron nl;cIeus as reflected by the isomer shift does not change very much while going