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Heteronuclear NMR studies of cobalamins. 11. Nitrogen-15 NMR studies of the axial nucleotide and amide side chains of cyanocobalamin and dicyanocobamides

✍ Scribed by Brown, Kenneth L.; Brooks, Harold B.; Zou, Xiang; Victor, Mark; Ray, Anjan; Timkovich, Russell


Book ID
126985055
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
497 KB
Volume
29
Category
Article
ISSN
0020-1669

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Absolute assignments were made of the side-chain amide proton and nitrogen resonances of a series of cobalamins (Cbls, derivatives of vitamin and two cobinamides [ Cbis, analogs in which the axial 5,6-B 12 ) dimethylbenzimidazole (Bzm) ligand has been chemically removed ] in water. The syn and anti