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Heterolytic and Homolytic N−H Bond Dissociation Energies of 4-Substituted Hantzsch 2,6-Dimethyl-1,4-dihydropyridines and the Effect of One-Electron Transfer on the N−H Bond Activation

✍ Scribed by Cheng, Jin-Pei; Lu, Yun; Zhu, Xiao-Qing; Sun, Yongkai; Bi, Feng; He, Jiaqi


Book ID
120898273
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
87 KB
Volume
65
Category
Article
ISSN
0022-3263

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✍ Meiyappan Muthuraman; Yvette Le Fur; Muriel Bagieu-Beucher; René Masse; Jean-Fra 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 213 KB

A set of three aryl dimethyl pyrimidinones have been studied and their crystal structures described in terms of networks of C+H'''O and C+H'''N hydrogen bonds. Two of the three molecules in this study di4er in the replacement of a chloro group by a methyl group and obey the chloro+methyl exchange ru