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Heterogeneous CeO2 catalyst for the one-pot synthesis of organic carbamates from amines, CO2 and alcohols

✍ Scribed by Honda, Masayoshi; Sonehara, Satoru; Yasuda, Hiroshi; Nakagawa, Yoshinao; Tomishige, Keiichi

Book ID
120354124
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
478 KB
Volume
13
Category
Article
ISSN
1463-9262

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An efficient one-pot synthesis of N-alky
An efficient one-pot synthesis of N-alkyl carbamates from primary amines using Cs2CO3
✍ Ralph Nicholas Salvatore; Jeremy A Ledger; Kyung Woon Jung πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 127 KB

A facile one-pot synthesis of N-alkyl carbamates is described. A primary amine, CO 2 , and an alkyl halide underwent a three-component coupling using cesium carbonate and tetrabutylammonium iodide (TBAI) giving rise to the resultant carbamate. In the presence of Cs 2 CO 3 , subsequent N-alkylation o