Heterogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate at Low Metal Salt Concentrations
β Scribed by Faucher, Santiago; Zhu, Shiping
- Book ID
- 126837848
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 166 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0888-5885
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π SIMILAR VOLUMES
## Abstract The reverse atom transfer radical polymerization of methyl methacrylate was investigated in different solvents: xylene, __N,N__βdimethylformamide, and pyridine. The polymerizations were uncontrolled, using 2,2β²βbipyridine as a ligand in xylene and pyridine because the catalyst (CuBr~2~/
## Abstract Microwave irradiation (MI) was applied to the atom transfer radical bulk polymerization of methyl methacrylate. The influence of the amount of the refluxing solvent used for controlling the polymerization temperature, irradiation power, irradiation time, and initiator concentration on t