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Heterocyclization of tropinone oximes and 3-methyl-3-azabicyclo[3.3.1.]-nonan-9-one with acetylene in a superbasic medium

โœ Scribed by A. V. Varlamov; L. V. Voskresenskii; T. N. Borisova; A. I. Chernyshev; A. N. Levov


Publisher
Springer US
Year
1999
Tongue
English
Weight
264 KB
Volume
35
Category
Article
ISSN
0009-3122

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The potential energy hypersurfaces for the triple inversion, from chair to boat and โฃ to โค conformations, are explored theoretically in 3w x azabicyclo 3.3.1 nonan-9-one and its N-methyl derivative, by using ab initio quantum-mechanical calculations. Both compounds are precursors of rigid analogs of