✦ LIBER ✦

Heterocyclization of primary amines with highly activated cyclopropanes: a new route to isoretronecanol

✍ Scribed by J.P. Celerier; M. Haddad; D. Jacoby; G. Lhommet

Book ID: 104228218
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 187 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96923-5

No coin nor oath required. For personal study only.

✦ Synopsis

A synthesis of dihydropyrroles is reported via nucleophilic homoallylic addition of activated cyclopropanes, followed by intramolecular @-enaminoester formation.

📜 SIMILAR VOLUMES

Mercuration demercuration of aliphatic i

Mercuration demercuration of aliphatic isocyanates: a new mild route to primary amines

✍ Corrado Malanga; Andrea Urso; Luciano Lardicci 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 218 KB

Electrophilic Activation and Cycloisomer

Electrophilic Activation and Cycloisomerization of Enynes: A New Route to Functional Cyclopropanes

✍ Christian Bruneau 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 818 KB

Electrophilic Activation and Cycloisomer

Electrophilic Activation and Cycloisomerization of Enynes: A New Route to Functional Cyclopropanes

✍ Christian Bruneau 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 8 KB 👁 1 views

Hydroaminomethylation of fatty acids wit

Hydroaminomethylation of fatty acids with primary and secondary amines — A new route to interesting surfactant substrates

✍ Arno Behr; Martin Fiene; Christian Buß; Peter Eilbracht 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 2 views

ChemInform Abstract: Mercuration-Demercu

ChemInform Abstract: Mercuration-Demercuration of Aliphatic Isocyanates: A New Mild Route to Primary Amines.

✍ C. MALANGA; A. URSO; L. LARDICCI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB

The reaction of pentacyanonitrosylferrat

The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: a new route to secondary amines

✍ Fabio Doctorovich; Cecilia Trápani 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 302 KB

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce