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Heterocyclic boronium ions. Reaction of diamine salts with sodium borohydride

✍ Scribed by Douglass, James E.; Fellman, Jack D.; Carpenter, Randall; Shih, Houng-Min; Chiang, Yu-Fen


Book ID
127235926
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
306 KB
Volume
34
Category
Article
ISSN
0022-3263

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Unexpected formation of 1,2-dihydro-2-az
✍ Ibolya Prauda; Mária Tóth-Lauritz; József Reiter 📂 Article 📅 2004 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 142 KB

## Abstract The reduction of different 2‐azolyl‐and azinylisoquinolinium salts with sodium borohydride in methanol was studied. Surprisingly, contrary to what is found in the literature 1,2‐dihydroisoquinoline derivatives were obtained. Their formation was attributed to the electron withdrawing cha