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Heterocomplexation of a Chiral Dipeptide and Quantitative Enantiomeric Enrichment of Nonracemic 1,1′-Bi-2-naphthol

✍ Scribed by Shan, Zixing; Xiong, Ying; Yi, Jing; Hu, Xiaoyun


Book ID
126268019
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
113 KB
Volume
73
Category
Article
ISSN
0022-3263

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Chiral 2,2-disubstituted cyclopropanecar
✍ Hyun Chang Kim; Soojin Choi; Hongdoo Kim; Kwang-Hyun Ahn; Jeong Hwan Koh; Jaiwoo 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 190 KB

The enantiomeric purities of secondary alcohols can be easily analyzed by GC and HPLC through derivatization to the esters of 2,2-disubstituted cyclopropanecarboxylic acids 1, and by ~H NMR analysis of the esters of 2,2-diphenylcyclopropanecarboxylic acid (Ib). In addition racemic l,l'-bi-2-naphthol