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Crystal engineering of chiral superstructures based on (R)-(+)-1,1′-bi-2-naphthol and the alkali derivatives of racemic (R,S)-1,1′-bi-2-naphthol

✍ Scribed by Grepioni, Fabrizia; Gladiali, Serafino; Scaccianoce, Laura; Ribeiro, Paulinha; Braga, Dario


Book ID
120174532
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
353 KB
Volume
25
Category
Article
ISSN
1144-0546

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Structural characterization of racemic 1
✍ Melanie Thoß; Rüdiger W. Seidel; Iris M. Oppel; Martin Feigel 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 683 KB

Racemic forms of 1,1 0 -bi-(2-naphthol) (BINOL) monopivalate (rac-1) and its 6-nitro substitute (rac-2) were structurally characterized by X-ray crystallography. Molecules of opposite chirality form dimers in the crystalline state of rac-1 through OAHÁ Á ÁO hydrogen-bonds between the free hydroxy an