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Heterobimetallic gold-palladium phosphine cluster complexes. X-ray crystal and molecular structure of [Au8Pd(PPh3)8](NO3)2

โœ Scribed by Ito, Larry N.; Johnson, Brian J.; Mueting, Ann M.; Pignolet, Louis H.


Book ID
126890450
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
459 KB
Volume
28
Category
Article
ISSN
0020-1669

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Halide derivatives of palladium-gold clu
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The reaction chemistry of [Pd(AuPPh&](NO 3 ) 2 with the halide ions Cl-, Br-and I-and with the pseudohalide CN-has been studied. Acetone solutions of [Pd(AuPPh,),](NO,), reacted with these ions to give the new Pd-Au clusters (I)Pd(AuPPh&(AuI)2, [Pd(AuPPh,),(AuBr),]+, Pd(AuPPh,),(AuCl), and Pd(AuPPh&