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Hetero-polynuclear complexes containing bridging diphenylphosphino-alkenes and -alkynes. The crystal structure of an Rh2{μ−ν1:ν2−P(Ph2) (CH2)3C≡CR}Co2 complex

✍ Scribed by Tania De Simone; Ron S. Dickson; Brian W. Skelton; Allan H. White

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 1007 KB
Volume: 240
Category: Article
ISSN: 0020-1693
DOI: 10.1016/0020-1693(95)04549-x

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo