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Hetero-arylboroxines: the first rational synthesis, X-ray crystallographic and computational analysis

✍ Scribed by Iovine, Peter M.; Gyselbrecht, Charles R.; Perttu, Emily K.; Klick, Cole; Neuwelt, Alexander; Loera, Jason; DiPasquale, Antonio G.; Rheingold, Arnold L.; Kua, Jeremy


Book ID
118268806
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
206 KB
Volume
29
Category
Article
ISSN
1477-9226

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Unusual peptides containing the 2,6-diam
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The stereocontrolled synthesis of peptides 6, 9 and 14, structural variants of 2,6-diaminopimelic acid, was carried out starting from the chiral synthon 1, easily obtained from L-valine. The configuration of the introduced stereogenic centres has been assigned on the basis of 1 H NMR spectroscopic d