𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Organometallic compounds of the lanthanides. 24. Synthesis and x-ray crystallographic characterization of the first organolanthanide derivative with a lanthanide-silicon bond

✍ Scribed by Schumann, Herbert.; Nickel, Siegbert.; Hahn, Ekkehardt.; Heeg, Mary J.

Book ID
127357916
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
295 KB
Volume
4
Category
Article
ISSN
0276-7333

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Organometallic Compounds of the Lanthani
Organometallic Compounds of the Lanthanides. 127 [1] Synthesis of Monomeric Bis(cyclopentadienyl)lanthanide Tetrahydroborates with Bulky Cyclopentadienyl Ligands. Single Crystal X-ray Structures of [(Ξ·5-C5Me5)2SmBH4(THF)] and [(Ξ·5-C5Me4Et)2Y(ΞΌ-H)2BH2(THF)]
✍ Herbert Schumann; Markus R. Keitsch; JΓΆrg Demtschuk; Stefan MΓΌhle πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 171 KB πŸ‘ 2 views

The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ΔΉnBH 4