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Helicity Inversion in Lanthanide(III) Complexes with Chiral Nonaaza Macrocyclic Ligands

✍ Scribed by Janusz Gregoliński; Jerzy Lisowski


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
146 KB
Volume
120
Category
Article
ISSN
0044-8249

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Helicity Inversion in Lanthanide(III) Co
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Controlling the chirality of metal complexes or supramolecular assemblies continues to be a challenging and fascinating area of research. [1] The chirality of these systems may be related, for example, to the spatial disposition of chelating ligands around a metal ion, [1a] to the formation of doubl

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## Abstract Lanthanide complexes of a hexaaza macrocyclic ligand containing a pyridine head unit (L) were synthesized (Ln = La–Lu, except Pm). The solid‐state structures of the corresponding La, Ce, Pr, Nd, and Lu complexes were determined by single‐crystal X‐ray crystallography, and they reveal th