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Heavier Alkaline Earth Amides as Catalysts for the Tischenko Reaction.

✍ Scribed by Mark R. Crimmin; Anthony G. M. Barrett; Michael S. Hill; Panayiotis A. Procopiou


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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Homoleptic Lanthanide Amides as Homogene
✍ Markus R. BΓΌrgstein; Helga Berberich; Peter W. Roesky πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 135 KB πŸ‘ 1 views

The homoleptic bis(trimethylsilyl)amides of Group 3 metals and lanthanides of the general type [Ln{N(SiMe 3 ) 2 } 3 ] (1) (Ln Y, lanthanide) represent a new class of Tishchenko precatalysts and, to a limited extent, precatalysts for the hydroamination/cyclization of aminoalkynes. It is shown that 1