The homoleptic bis(trimethylsilyl)amides of Group 3 metals and lanthanides of the general type [Ln{N(SiMe 3 ) 2 } 3 ] (1) (Ln Y, lanthanide) represent a new class of Tishchenko precatalysts and, to a limited extent, precatalysts for the hydroamination/cyclization of aminoalkynes. It is shown that 1
β¦ LIBER β¦
ChemInform Abstract: Homoleptic Lanthanoid Amides as Homogeneous Catalysts for Alkyne Hydroamination and the Tishchenko Reaction.
β Scribed by Markus R. Buergstein; Helga Berberich; Peter W. Roesky
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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