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ChemInform Abstract: Lanthanide Formamidinates as Improved Catalysts for the Tishchenko Reaction.

✍ Scribed by Agustino Zuyls; Peter W. Roesky; Glen B. Deacon; Kristina Konstas; Peter C. Junk


Publisher
John Wiley and Sons
Year
2008
Weight
39 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Homoleptic Lanthanide Amides as Homogene
✍ Markus R. BΓΌrgstein; Helga Berberich; Peter W. Roesky πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 135 KB

The homoleptic bis(trimethylsilyl)amides of Group 3 metals and lanthanides of the general type [Ln{N(SiMe 3 ) 2 } 3 ] (1) (Ln Y, lanthanide) represent a new class of Tishchenko precatalysts and, to a limited extent, precatalysts for the hydroamination/cyclization of aminoalkynes. It is shown that 1