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Heat resistant matrix resins based on addition-type bisimidobenzimidazoles

โœ Scribed by John A. Mikroyannidis


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
377 KB
Volume
27
Category
Article
ISSN
0014-3057

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โœฆ Synopsis


Bismaleimides containing benzimidazole moieties were synthesized and characterized by i.r. and ~H-NMR spectroscopy. The DTA thermograms of polymer precursors showed exotherms at 139-210 ยฐ attributed to the thermally induced crosslinking reactions. The curing temperatures were shifted to higher temperatures with decreasing concentration of maleimide groups in monomers. The thermal stabilities of cured resins were evaluated by TGA in N2 and air atmospheres. They were stable up to 317-347 ยฐ both in N 2 and air and formed an anaerobic char yield of 75% at 800 ยฐ.


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A maleimide-functional phenolic resin was reactively blended with an allyl-functional novolac in varying proportions. The two polymers were coreacted by an addition mechanism through Alder-ene and Wagner-Jauregg reactions to form a crosslinked network system. The cure characterization was done by di